Characterizing Cross Sections and Thin Structures Using NanoIR Spectroscopy

NanoIR is highly suited for identification of organic components that cannot be
conventionally analyzed by other organic analysis techniques such as FTIR or Raman.

Atomic force microscopy-based infrared spectroscopy (AFM-IR, NanoIR) provides vibrational spectroscopic information with high spatial resolution (<30 nm). As a result, NanoIR is highly suited for the identification of organic components in size regimes that cannot be conventionally analyzed by other organic analysis techniques such as FTIR, which is typically limited to tens of microns in analytical area, and even Raman, which is limited to approximately one micron in analytical area.

In this example, two polymer structures were examined: 1) a cross section comprised of three polymers and 2) a thin polymer contaminant on a silicon wafer.

Optical image of the polymer cross section, blue box is the analysis size for FTIR and the red box shows the imaged region in NanoIR.

Optical image of the polymer cross section, blue box is the analysis size for FTIR and the red box shows the imaged region in NanoIR.

NanoIR spectra taken on the contaminant (blue) and from a bulk film of polystyrene (black).

NanoIR spectra taken on the contaminant (blue) and from a bulk film of polystyrene (black).

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