Tensiometry

Tensiometry is the measurement of interfacial tension, typically of the interface between a liquid and a solid, gas, or another liquid.

EAG Laboratories performs dynamic contact angle and force tensiometry measurements using the Dataphysics DCAT21. The DCAT21 is equipped with a high precision balance and z-axis variable speed stage for reproducible measurements of the change in apparent mass of a sample when in contact with a liquid. All measurements can be performed under temperature controlled conditions from -20 ºC to 100 ºC.

Liquids

Surface Tension: The surface tension of a liquid in air can be measured using the Wilhelmy plate method.

Liquid-Liquid Interfacial Tension: The du Noüy ring method can be used to determine the interfacial tension between two liquids by measuring the tensile force required to breach the interface.

Density: The density of a liquid can be measured with high precision by measuring the buoyancy of a solid with well-defined geometry when it is immersed in the liquid.

Solids

Density: The density of solids can be analyzed by measuring the mass of the solid and calculating the volume by the buoyant force when the solid is immersed in a liquid of known density.

Dynamic Contact Angle: The contact angle of a liquid-solid interface can be measured by the tensile force applied while the solid is being immersed (advancing contact angle) and withdrawn (receding contact angle) from a liquid with known or measured surface tension and density. Thin films can also be measured in this manner.

Powders

Density: The density of a powder can be determined by the same measurement as the density of a solid.

Contact Angle: By treating the interstitial space of a powder as though it were a bundle of capillaries, the relationship between the contact angle and the capillary constant can be determined.

Ideal uses
  • Characterization of coatings, films, fibers and powders to investigate their hydrophobic/hydrophilic properties
  • Investigate changes in surface finish
  • Measure physical properties of materials
  • Raw materials fingerprinting
  • Sample purity determination (potentially in conjunction with other methods)
  • Quality assurance and quality control
Technical Specifications
  • Temperature control -20 to 100 °C
Strengths
  • Non-destructive method
  • Surface tension can be measured in many different solvents
  • Contact angle and surface tension measurements provide information regarding fluid properties, liquid/liquid interfaces and solid-liquid interactions
  • An excellent way to characterize coatings and films; can be used on single side coated samples
  • Can be used on fibers
  • Density of liquids, solids and powders can be used to track physical properties
Limitations

Volume requirements:

  • For density measurements, sample requirements are 40 mL liquid and ~1 mL powder
  • For surface tension measurements, sample requirement is 20 mL
  • For contact angle measurements, requirements are: ~20 mL liquid, ~30 mL powder and ~5 mm length of solid material
  • Cannot be used on strong acids

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