Structure and composition analysis of Li-ion batteries materials at different scales are critical to understand their electrochemical performance (such as capacity fade and lithiation/delithiation pathways). A battery cell’s behavior is directly related to how the slurry gets assembled on the electrode. The performance has a strong correlation to the primary and secondary particle network inside the electrode. Further the lithium-ion movement and the electrode/electrolyte interaction start at the atomic level. So, characterization of the electrodes at different length scales is necessary to fully understand the battery performance.